GROSIZE-200 - Oxidized Starch for Spray & Sizing of Paper

Corrugated paper box is used mainly for shipping / transportation and storage of variety of items for their strength and durability. In the process of making box mainly paper and gum adhesives are major players which determine strength of the box. More moisture in the box will cause lower compression strength of the box. Lower compression causes collapse of stacked boxes and thus damage to the goods packed inside.

So control of moisture in corrugated box means controlling moisture in paper and in gum adhesives used in box making.

1.Controlled moisture in paper.

The major component of paper, cellulose fiber, is hygroscopic in nature and therefore tends to absorb moisture from a damp or humid atmosphere or release moisture in dry atmosphere. When paper gains moisture corrugated box loses its bursting strength (BS) and compression strength (CS) and when it loses moisture corrugated box develops the cracking or board breaking problem.

To avoid this cracking of corrugated sheets use of sprayer to spray water onto base paper, changing of machine speed and adjustment of the flexible paper-lead roller to cut preheat area are required. Avoid exposure of paper reels in open sun heat which will bring down paper moisture substantially to cause cracking of corrugated sheets at the end.

To overcome excess moisture in corrugated board use of correct paper cob, changing machine speed, use of preheaters etc. are some of the solutions.

2. Moisture control through gum adhesives

Gum adhesives play major role in avoiding excess moisture in corrugated box. Type and quality of starch used in adhesives, type of fillers used, modifications to starch and chemicals used in the gum adhesives are major players in causing excess moisture in corrugated board.

a) Gel temperature of gum is important in automated plants and in single face. High pin adhesion at low temperature gives complete dry liners and board. If gum fails to get gelatinized immediately when it reaches heaters at the set speed of machine, it fails to develop stronger bond adhesion and develops the tendency of gaining moisture from atmosphere in later stage even after complete drying.

b) Type of starch used and specific modification to starch to develop moisture resistance are very important factors. Usually hydrolysis of starch with the use of acid and then use of strong alkali to get viscous gum is a common product which is available in the market. These type of adhesives are bound to gain moisture in damp atmosphere and humid climatic conditions. Special modification treatment to high quality starch to develop moisture resistance is required.

c) Different fillers are used in gum adhesive making to bring down cost and make our adhesives cheaper in the market of competition. Very low cost fillers such as different flours, clay, Urea etc. are used which pay no role in gum quality than reducing price substantially. Flour, clay or urea are more of hygroscopic in nature and cause more and more moisture gain whenever gets opportunity.

d) Chemicals used in gum adhesives such as Sodium Hydroxide (caustic soda) is highly hygroscopic and not only absorbs moisture but carbon dioxide, sulfur dioxide in the air. It is also highly deliquescent and absorbs moisture to form an aqueous solution. More moisture means lesser bursting and compression strength which results in collapse of stacked boxes.

Moisture resistance of box and waterproofing of box are two different concepts. Moisture resistance is applicable only in damp conditions or humid climate where as water proofing is applicable only when box comes in direct contact with water.

Humid air has a density of approximately 1.225 kg/m³ and density of water is 997 kg/m³. Gum lines of moisture resistant grade powder adhesives can on can resist moisture due to its very low density but can’t resist direct water due to its very high density. When box comes in direct contact with water not only gum but even paper starts absorbing it and thus collapse.

So what is important is moisture resistance and not waterproofing of gum adhesive. Stacked box should stand in any climatic condition and not in water. If at all waterproofing is demanded then coat of waterproof chemical is applied to paper. Always go for moisture resistant grade adhesives though costly as they prove to be highly profitable in actual practice.

Fungus mold is everywhere. There is realistically nothing you can do to stop mold spores from being on your box. They're everywhere. As soon as a door or window is opened, mold spores come in. As soon as you enter your factory, mold spores that were on you are now in your factory.

How mold germinate from spores and grow (Dust/moisture/temperature)

Mold consumes just about anything organic including things like dust. No matter how clean you try to keep your factory, there will be always still be some dust in it. So, other than keeping a relatively clean factory, mold's food source is something that is very hard to control.

Moisture source is the most controllable source. Moisture sources can be actual moisture gain by adhesives used and high cob value papers and even humidity. Without moisture, mold cannot even start to germinate. Control the moisture and you control the mold.

Different mold species need different temperatures, but most are within the comfort levels we have in our factories. Caustic based gum used by us not only absorbs moisture but also provides temperatures which helps to grow mold. So use of Sodium hydroxide (caustic soda) based gum is what we consider an uncontrollable source.

Always use Natural Chemical free gum adhesives to avoid Fungus / mold growth in box.

Grodex moisture resistant Powder adhesives are totally Sodium Hydroxide (caustic soda) free and does not provide source for development of mold / fungus in box.

During production of corrugated boards, many have met the problems caused by inaccurate control of moisture, whether by higher (leading to collapse, flute-exposure) or lower moisture (leading to board breaking). Moisture control is a crucial issue in production and procession of corrugated boards.

Not enough water in board would make them to be crisp and easy to breakdown. But moisture control is a complex process affected by many elements.Demand conforming base paper from suppliers. Not only board but even base paper will crack if moisture level of paper is below 5%. Store base paper in separate warehouses with temperatures within 15℃ and 20℃, and relative humidity within 30% and 40%

Don’t expose base paper in the open air, otherwise the moisture of base paper would change, and moisture in the ends and middle part would vary from one another, which would make it harder for further procession.

Overheating of the single facer and hot plates is one of the reason of cracking or breaking of board. Adjustments of speed and use of water sprayer is required to maintain moisture level of board.

Warp means “corrugated sheet or box to become bent or twisted out of shape, typically as a result of the effects of heat or dampness”. Bent or twisted corrugated board results in excessive scrap, waste, and reduced production rates.

What Causes Warp?

• Moisture imbalance between the top and bottom liners
• Tension imbalance between the top and bottom liners
• Different types and grades of linerboard and inner linerboard. Generally, linerboard is better than inner linerboard.

Check following points to correct warp issue-

In the process of applying adhesive to the liners, there should be a delicate balance of heat and bonding between the layers with the adhesive consistently applied to the flute tips. Exposure to high humidity, applying excessive adhesive, inconsistent adhesive application and improper glue roll to paper speeds will all cause moisture imbalance which in turn leads to warp in the cross-machine direction.

The main technical parameters of the linerboard and inner linerboard are different. From the perspective of carton performance or the user's cost reduction, the linerboard and inner linerboard are required to be different.

Difference in Moisture content of papers due to the differences of supplier, transportation inventory and other environmental humidity. Some moisture content of linerboard are larger than inner linerboard, some are smaller.

Big difference in GSM and BF of linerboard and inner linerboard is also one of the reason of warp.

The moisture content of the same batch of paper may differ. The moisture content of one part of the paper is different from that of the other part, or the two ends of the paper, the outer edge and the inner core.

If vapor spray device is not used correctly, or there is no spray device on the machine.

If the paper after the preheating of moisture loss time is insufficient, or the environment humidity, poor ventilation, improper speed of the production line.

In a Single side corrugated machine, glue amount is improper due to uneven gum roller can cause uneven shrinkage rate of cardboard.

Techniques for reducing moisture related warp include:

• Increase corrugator speed (if possible)
• Use of proper temperature control panels to avoid excessive heat.
• In a single facer with electrical heaters, never use very high capacity heaters than what recommended by machine makers as per the size and speed of machine.
• Keep adhesive settings to minimum. More adhesive means more water which comes through adhesive.
• Equalize the temperature across the width of the sheet by inspecting for parallel misalignment between the preheater drums and wrap arms, and make proper alignment adjustments so that they are parallel one another

Tension Issues

A difference in tension between the top and bottom of the sheet can result in machine direction warp. Main reasons for this tension related warp are:

• Preheaters turning improperly (or not at all)
• Rolls not turning freely
• Inadequately functioning roll stand brakes
• Poorly maintained web guides
• Excessive drag in the hot plate section

Washboard is an undesired effect on the surface of corrugated sheet (uneven corrugation flute markings). The main reason of washboard effect on corrugated board is excess moisture retention in board and / or shrinkage of top paper due to poor quality gum adhesive.

Minimum application of high solid natural gum is must to get excellent finish to the box. If gum quality is poor, operator releases excess gum to ensure perfect lamination of top paper and this is the main reason of washboard effect on the top surface of the corrugated sheet. If viscosity of gum is too high, gum consumption will increase to cause washboard at the end. Use of Sodium Hydroxide (caustic soda) and addition of cheap fillers in gum powder such as urea, sault etc. causes shrinkage of top surface paper.

Insist gum supplier to give high solids, low viscosity and chemical free gum made of pure starch without any fillers. Quality high solid gum will give operator a confidence to release minimum possible gum. Minimum release of gum not only improves aesthetics by solving washboard but also increase overall strength of box.

Grodex moisture resistant grade powder adhesives for corrugated paper board industry are made from finest quality combination of starch, are of high solids and low viscosity. Minimum application of these adhesives give more than double the coverage than other normal gum available in the market. Grodex adhesives improves aesthetics of box substantially and are suitable even for high quality virgin imported papers where black lining is a common issue.

Let us try to understand drying process.

In summer due to dry & hot weather conditions, box dries automatically & very fast. But in rainy & winter season, it takes longer time for complete drying or in most of the cases box regains moisture even after complete drying.

In summer, we wash clothes at our home & clothes get dry within few hours, without doing anything. But in rainy & winter season clothes doesn’t get dry so easily. We have to do so many things to dry them completely. We keep wet clothes below ceiling fan & if they still found wet we apply heat by pressing them with iron.

Corrugated box is made of paper which contains wood fibers. Box will not dry automatically in humid climatic conditions. Same thing we have to do with corrugated boxes to dry them fully if we want faster drying and faster delivery.

Put them either in front of air circulator or in drying chamber to apply heat.

Now the problem starts when box regains moisture even after complete drying. Here role of gum adhesive is very important. If you want to overcome problem of moisture regain always use gum which doesn’t contain Sodium Hydroxide (caustic Soda). Caustic soda is hygroscopic and always regains moisture whenever it gets an opportunity.

Use high solids, low viscosity gum made of pure quality starch. Release minimum gum which will promote faster drying.

Grodex Moisture Resistant Powder Adhesives fast drying and give moisture resistant gum films on drying which permanently prevents regaining of moisture.

It means on complete drying -

1. b/s & c/s achieved on drying remain forever in any weather condition & even in refrigeration.

2. Box remains dry & avoids fungus growth.

3. Rusting of pins is avoided.

4. Excellent finish & aesthetic of box is achieved by avoiding warp & wash board.

With the use of low quality chemical based gum, even if you try & dry your boxes, they will gain moisture even after complete drying. But grodex adhesives resist moisture and keeps your boxes dry forever.

Stitching wire are available either Electroplated or Hot Dipped. In both the cases it is made of MS and coated to prevent rust. Such coating can delay rusting of pins but can’t avoid rusting of pins totally.

Pin gets rusted when it comes in to constant contact of water / moisture. Chemical used in gum adhesives such as Sodium Hydroxide (caustic soda) is highly hygroscopic and not only absorbs moisture but carbon dioxide, sulfur dioxide in the air. It is also highly deliquescent and absorbs moisture to form an aqueous solution. Caustic soda is also highly corrosive. Thus it promotes more moisture in the corrugated box through gum which causes rusting of stitching pins.

Always use gum without any chemicals (free of caustic soda) to overcome the problem of rusting of stitching wire / pins.

In the process of export corrugated box travels in a container in a deep sea where humidity goes very high. If gum adhesive used in such box consists of Sodium Hydroxide (caustic soda) gum lines will start gaining moisture and will cause following problems –

Drop in Bursting strength and compression strength of box resulting in collapse and loss of packed goods.

Chances of fungus on the box due to higher moisture.

Rusting of pins.

To avoid these problems always use gum adhesives which is totally chemical free and which gives guaranteed moisture resistance in any weather condition.

Grodex Moisture Resistant Powder Adhesives are totally chemical free (doesn’t contain caustic soda). Modification of starch is done with unique process with the state of the art technology which guarantees moisture resistant gum film lines after complete drying. It means box made of grodex powder adhesives gives guaranteed permanent bursting strength and compression strength even in deep sea in very high humid conditions. Moreover it improves aesthetics of box by giving great finish and no washboard issues.

As a practice corrugators do believe that paper used in the box determines bursting and compression strength. Which is very much true.

But on the other hand gum adhesive used in the box making decreases bursting strength and compression strength of box, if low quality chemical based gum adhesives are used.

How gum plays a role –

• Type of starch used and specific modification to starch to develop moisture resistance are very important factors. Usually hydrolysis of starch with the use of acid and then use of strong alkali to get viscous gum is a common product which is available in the market. These type of adhesives are bound to gain moisture in damp atmosphere and humid climatic conditions. Special modification treatment to high quality starch to develop moisture resistance is required.
• Different fillers are used in gum adhesive making to bring down cost and make our adhesives cheaper in the market of competition. Very low cost fillers such as different flours, clay, Urea etc. are used which pay no role in gum quality than reducing price substantially. Flour, clay or urea are more of hygroscopic in nature and cause more and more moisture gain whenever gets opportunity.
• Chemicals used in gum adhesives such as Sodium Hydroxide (caustic soda) is highly hygroscopic and not only absorbs moisture but carbon dioxide, sulfur dioxide in the air. It is also highly deliquescent and absorbs moisture to form an aqueous solution. More moisture means lesser bursting and compression strength which results in collapse of stacked boxes

Problems caused due to moisture in Corrugated Box

Only paper, how superior quality is, without corrugation process can’t give stacking strength for storage and transportation of different goods and therefore flute formation and adhesives applied to both the sides of flutes, determines strength of corrugated box. If these gum lines starts absorbing moisture from air, box starts losing its compression and collapses on stacking.

Therefore moisture resistance of gum lines on the paper from both the sides of flute is essential to guarantee unchanged compression strength of corrugated box. Fast drying of corrugated sheet and its moisture resistance are two different concepts. Gum which is drying fast need not have moisture resistance and vice a versa.

Major problems caused due to moisture gain in box

Box loses its compression strength and collapses in stacking position

Corrugator starts using higher grade papers to achieve desired strength which eats profit which has already narrowed due to tough completion.

Advantages of good quality moisture resistant adhesives

Guaranteed moisture resistance and permanent compression / bursting strength in any climate conditions and even in export of goods when box travels offshore in deep sea where relative humidity goes very high.

Bursting and compression strength of box improves substantially. This helps corrugators to save in terms of paper by using lower grades instead of higher grade papers. Paper cost consists of almost 97% of total box cost. Savings in paper means saving in 97% cost of box. Thus corrugator gets an opportunity to grab huge hidden profits by using quality gum adhesives. More margins helps him to become more competitive in the market and better quality and improved aesthetics of box helps him fetch more orders in open market, which further increases market share with improved margins.

Grodex moisture resistant powder adhesives are guaranteed proved moisture resistant and helps corrugators to mint money in highly competitive market.